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Journal of the Chemical Society, Dalton Transactions. The structure of compound 2 is made up of centrosymmetric bipym-bridged dinuclear [Cu 2 bipym C 5 O 5 2 H 2 O 2 ] units in which the copper atom exhibits a slightly distorted square-pyramidal co-ordination, with two bipym nitrogens and two croconate oxygens defining the equatorial plane whereas a water molecule occupies the axial position.
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How does Europe PMC derive its citations network?
3,4,5-Trioxocyclopentene-1,2-diolate | C5O5 | ChemSpider
This H-bond interaction leads to a quadratic regular layer where each [Fe C 5 O 5 2 H 2 O 2 ] 2- anion is connected to its four neighbors in the plane through four equivalent H-bonds.
The intradimer metal-metal separation is 5.
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This model reproduces quite satisfactorily its magnetic properties but only above the maximum. The structure can be viewed as formed by alternating layers of trans-diaquabis croconato ferrate II complexes and layers containing the monoprotonated croconate anions, HC 5 O 5 -and noncoordinated water molecules. Fetching data from CrossRef.
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