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How does Europe PMC derive its citations network? Reproduced material should be attributed as follows: Journal of the Chemical Society, Dalton Transactions. Jump to site search. Back to tab navigation Download options Please wait

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Reproduced material should be attributed as follows: V5o5 do not have JavaScript enabled. Either your web browser doesn’t support Javascript or it is currently turned off. A H-bond network is also formed between the coordinated water molecule and one oxygen atom of the coordinated croconate.

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Cyclopentanepentone

Journal of the Chemical Society, Dalton Transactions. The structure of compound 2 is made up of centrosymmetric bipym-bridged dinuclear [Cu 2 bipym C 5 O 5 2 H 2 O 2 ] units in which the copper atom exhibits a slightly distorted square-pyramidal co-ordination, with two bipym nitrogens and two croconate oxygens defining the equatorial plane whereas a water molecule occupies the axial position.

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In the latter case, please turn on Javascript support in your web browser and reload this page. For reproduction of material from PPS: Go to our Instructions for using Copyright Clearance Center page c55o5 details. XX is the XXth reference in 5co5 list of references. CitePeer Related Articles http: Back to tab navigation Download options Please wait Although this second model might still be improved since there is also an extra contribution due to the presence of ZFS in the Fe II ions, it confirms the presence of weak ferromagnetic F5o5 interactions through H-bonds in compound 1 which represents one of the rare examples of ferromagnetic coupling via H-bonds.

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This H-bond interaction leads to a quadratic regular layer where each [Fe C 5 O 5 2 H 2 O 2 ] 2- anion is connected to its four neighbors in the plane through four equivalent H-bonds.

The intradimer metal-metal separation is 5.

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This model reproduces quite satisfactorily its magnetic properties but only above the maximum. The structure can be viewed as formed by alternating layers of trans-diaquabis croconato ferrate II complexes and layers containing the monoprotonated croconate anions, HC 5 O 5 -and noncoordinated water molecules. Fetching data from CrossRef.

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